Novel SOFC anodes for the direct electrochemical oxidation of hydrocarbons

نویسندگان

  • Raymond J. Gorte
  • John M. Vohs
چکیده

Recent developments in solid-oxide fuel cells (SOFC) that electrochemically oxidize hydrocarbon fuels to produce electrical power without first reforming them to H2 are described. First, the operating principles of SOFCs are reviewed, along with a description of state-of-the-art SOFC designs. This is followed by a discussion of the concepts and procedures used in the synthesis of direct-oxidation fuel cells with anodes based on composites of Cu, ceria, and yttria-stabilized zirconia. The discussion focuses on how heterogeneous catalysis has an important role to play in the development of SOFCs that directly oxidize hydrocarbon fuels.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Quantifying the Role of Cerium Oxide as a Catalyst in Solid Oxide Fuel Cell Anodes

Title of Document: QUANTIFYING THE ROLE OF CERIUM OXIDE AS A CATALYST IN SOLID OXIDE FUEL CELL ANODES Steven C. DeCaluwe, Doctor of Philosophy, 2009 Directed By: Associate Professor Gregory S. Jackson, Department of Mechanical Engineering Solid Oxide Fuel Cells (SOFCs) are an important electrochemical power conversion device, due largely to their high efficiencies and ability to directly oxidiz...

متن کامل

Novel SOFC Anodes for the Direct Electrochemical Oxidation of Hydrocarbon

This paper describes recent developments in solid-oxide fuel cells (SOFC) that use Cu-based cermets as the anode for direct oxidation of hydrocarbon fuels, including liquids such as gasoline, to generate electrical power without the need for first reforming that fuel to H2. Cu-YSZ cermets were found to be stable in hydrocarbon environments, but exhibited low performance for direct oxidation. Re...

متن کامل

Electrochemical Oxidation Kinetics of Hydrogen and Higher Hydrocarbon Fuels on Solid Oxide Fuel Cells

Title of Document: ELECTROCHEMICAL OXIDATION KINETICS OF HYDROGEN AND HIGHER HYDROCARBON FUELS ON SOLID OXIDE FUEL CELLS. Oktay Demircan, Ph.D., 2007 Dissertation Directed By: Professor Bryan W. Eichhorn, Department of Chemistry and Biochemistry Solid oxide fuel cells (SOFCs) are promising electrochemical energy converting devices due to their ability to use not only hydrogen but also hydrocarb...

متن کامل

Recent Progress in SOFC Anodes for Direct Utilization of Hydrocarbons

There would be significant advantages to having anodes for solid oxide fuel cells (SOFC) that were capable of directly utilizing hydrocarbon fuels. Because conventional Ni-based anodes catalyze the formation of carbon fibers, new anode compositions are required for this application, but most of the materials that have been proposed exhibit either limited thermal stability or poor electrochemica...

متن کامل

Engineering Composite Oxide SOFC Anodes for Efficient Oxidation of Methane

Ceramic anodes for solid oxide fuel cells SOFCs were prepared by aqueous impregnation of nitrate salts to produce composites with 45 wt % La0.8Sr0.2Cr0.5Mn0.5O3 (LCSM)in a 65% porous yttria-stabilized zirconia (YSZ) scaffold. Scanning electron micrographs indicate that the LSCM coats the YSZ pores following calcination at 1473 K. Composites produced in this manner exhibit conductivities at 1073...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2016